Jisun Yoo1, Eunhee Cha1, Jeunghee Park1*, and Soo A Lim2*유지선1·차은희1*·박정희1·임수아2*
Department of Chemistry, Korea University, Sejong 339-700, Korea
1Dept. of pharmaceutical engineering, Hoseo University, Asan, Chungnam 336-795, Korea
2Department of Green Engineering, College of engineering, Sangmyung University, C-411 Main Building,
31 Sangmyungdae-gil, Dongnam-gu, Cheonan 31066, Republic of Korea1고려대학교 신소재화학과, 2호서대학교 제약공학과
Photoelectrochemical water splitting has been considered as the most promising technology
for generating hydrogen energy. Transition metal dichalcogenide (TMD) compounds
have currently attracted tremendous attention due to their outstanding ability towards the catalytic
water-splitting hydrogen evolution reaction (HER). Herein, we report the synthesis
method of various transition metal dichalcogenide including MoS2, MoSe2, WS2, and WSe2
nanosheets as excellent catalysts for solar-driven photoelectrochemical (PEC) hydrogen evolution.
Photocathodes were fabricated by growing the nanosheets directly onto Si nanowire (NW)
arrays, with a thickness of 20 nm. The metal ion layers were formed by soaking the metal chloride ethanol solution and subsequent sulfurization or selenization produced the transition
metal chalcogenide. They all exhibit excellent PEC performance in 0.5 M H2SO4; the photocurrent
reaches to 20 mA cm-2 (at 0 V vs. RHE) and the onset potential is 0.2 V under AM1.5
condition. The quantum efficiency of hydrogen generation is avg. 90%. The stability of MoS2
and MoSe2 is 90% for 3h, which is higher than that (80%) of WS2 and WSe2. Detailed structure
analysis using X-ray photoelectron spectroscopy for before/after HER reveals that the Si-
WS2 and Si-WSe2 experience more oxidation of Si NWs than Si-MoS2 and Si-MoSe2. This can
be explained by the less protection of Si NW surface by their flake shape morphology. The
high catalytic activity of TMDs should be the main cause of this enhanced PEC performance,
promising efficient water-splitting Si-based PEC cells.
Keyword : Transition Metal, Dichalcogenide, Nanomaterial, Photoelectrochemical Cells, Water