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한국전기화학회 한국전기화학회

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Vol.22, No.3, August 2019

Improving the Electrochemical Properties of Lithium Terephthalate-based Lithium-Organic Battery with A Graphite Coated Current Collector흑연 코팅 집전체를 이용한 Lithium Terephthalate 기반 리튬-유기 이차전지의 전기화학적 특성 개선
JKES Vol.22, No.3, pp.122-127, August 2019
DOI : 10.5229/JKES.2019.22.3.122
O Hyeon Kwon, Jong Bin Kim, and Jae-Kwang Kim*권오현·김종빈·김재광*
Department of Energy Convergence Engineering, Cheongju University, Cheongju, Chungbuk, 28503, Republic of Korea청주대학교 에너지융합공학과
In this study, we investigate the electrochemical performance of lithium terephthalate (LTA) battery using graphite coated metal current collector to overcome the disadvantages of organic batteries which is high interfacial resistance between current collector and electrode. The LTA anode material is synthesized by acid-based ion exchange reaction without impurities. The contact properties between stick-type LTA-based electrode and graphite coated current collector are estimated by the cross-section SEM and EIS. The graphite coated current collector significantly reduced the interfacial resistance of the LTA battery. The second discharge capacities of bare current collector LTA and graphite coated current collector LTA batteries are 107.6 mAh/g and 148.8 mAh/g at 0.1C, respectively. The graphite coated current collector LTA batteries show higher cycle life, higher discharge capacity, and higher rate-capability than bare LTA batteries.
Keyword : Lithium Terephthalate, Current Collector, Charge Transfer, Electrochemical Performance, Organic Battery

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